The goal of this puzzle is to distinguish between strong coupling and peak overlap.
For the following 1H NMR spectrum, are the 1H signals at 7.58-7.59 ppm exhibiting strong coupling or are they two overlapping multiplets or both?
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It does not look like exclusively strong coupling to me. For that magnitude of roofing I would expect the partner at about 7.7 ppm or closer.
Other than classic experiments, a pure shift spectrum would help interpreting overlap situations.
Posted by: Adolfo | October 04, 2010 at 02:23 PM